Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 163, Issue 13, Pages A2571-A2578Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0321613jes
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Funding
- NSERC
- 3M Canada under the Industrial Research Chairs program
- Walter C. Sumner Foundation
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Ethylene carbonate is a co-solvent used in virtually every lithium ion cell produced today because it enables operation of both the positive and negative electrodes. Most battery scientists believe ethylene carbonate is essential. Surprisingly, totally removing all ethylene carbonate from typical organic carbonate-based electrolytes and adding small amounts of electrolyte additives creates cells that are better than those containing ethylene carbonate. For example an electrolyte of only 2% vinylene carbonate and 98% ethyl methyl carbonate, with selected additives, provides excellent performance to Li[Ni0.4Mn0.4Co0.2]O-2/graphite cells cycled up to 4.4 V which increases their energy density by at least 10%. The cells have low impedance, low rates of electrolyte oxidation, good graphite passivation, low gas generation, acceptable conductivity and low cost. This discovery opens an entirely new space for electrolyte development. (C) The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.
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