4.6 Article

Solar-light-driven photocatalytic degradation of pharmaceutical pollutants utilizing 2D g-C3N4/BiOCl composite

Related references

Note: Only part of the references are listed.
Article Environmental Sciences

Construction of multifunctional NH2-UiO-66 metal organic framework: sensing and photocatalytic degradation of ketorolac tromethamine and tetracycline in aqueous medium

Manpreet Kaur et al.

Summary: In this study, aminofunctionalized zirconium-based metal organic framework was successfully synthesized and exhibited excellent fluorescence behavior and photocatalytic removal efficiency, making it suitable for monitoring and degrading specific pharmaceuticals in water.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Engineering, Chemical

Construction of g-C3N4/BiOCl/CdS heterostructure photocatalyst for complete removal of oxytetracycline antibiotic in wastewater

Teeradech Senasu et al.

Summary: One vital topic in photocatalysis research is the development of novel nanomaterials for the degradation of toxic pollutants in water under visible light. In this study, a g-C3N4/BiOCl/CdS heterojunction was successfully synthesized via a hydrothermal method for complete removal of oxytetracycline (OTC) antibiotic in wastewater. The ternary heterostructure effectively suppressed electron-hole recombination, resulting in enhanced photocatalytic activity. Full removal of OTC was achieved under natural sunlight irradiation, following a first-order reaction with a maximum rate constant of 0.023 min-1. The prepared photocatalyst exhibited structural stability and high performance even after multiple uses. Photogenerated holes played a critical role in the OTC removal, while electrons and hydroxyl radicals had a subordinate role. Charge transfer at the interface of the ternary heterojunction was proposed to be of Z-scheme type. This work demonstrates a promising strategy for the complete detoxification of harmful OTC antibiotic in the environment by creating an enhanced photoactive ternary heterojunction.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Chemical

Formation and textural characterization of size-controlled LaFeO3 perovskite nanoparticles for efficient photocatalytic degradation of organic pollutants

Kamal M. S. Khalil et al.

Summary: A series of LaFeO3 perovskite nanoparticles were successfully synthesized by a sol-gel method, and the influence of citric acid to metal ratio on their structure and photocatalytic performance was investigated.

ADVANCED POWDER TECHNOLOGY (2022)

Review Environmental Sciences

Advanced catalytic ozonation for degradation of pharmaceutical pollutants-A review

Eliasu Issaka et al.

Summary: The advanced catalytic ozonation process shows significant effectiveness in removing refractory organic compounds and degrading toxic organic pollutants in wastewater. Heterogeneous catalytic ozonation can effectively overcome the disadvantages of homogeneous catalytic ozonation, providing higher catalytic stability and efficiency.

CHEMOSPHERE (2022)

Article Environmental Sciences

Effective promotion of g-C3N4 photocatalytic performance via surface oxygen vacancy and coupling with bismuth-based semiconductors towards antibiotics degradation

Farzad Hasanvandian et al.

Summary: In this research, a novel BCO/N-CN composite was synthesized by introducing a new 1D/2D structure and creating surface oxygen vacancy (V-O) to serve as an efficient electron transfer highway. The composite showed excellent catalytic performance in the photodegradation of levofloxacin (LVFX) and maintained high stability over multiple reaction cycles. This study provides new insights into improving interfacial contact between components of heterojunctions and sheds light on charge migration behavior for efficient Z-type heterojunctions.

CHEMOSPHERE (2022)

Article Engineering, Electrical & Electronic

Flower-Like BiOCl/g-C3N4 Hybrid with Oxygen Vacancies Assembled by Nanosheets: In Situ Pyrolysis Associated with Ultrasonic Process and Photocatalytic Properties

Jinsong Xie et al.

Summary: This study describes a method for synthesizing flower-like p-n-type BiOCl/g-C3N4 nanosheets assembly using in situ ultrasonic treatment for enhancing the visible-light degradation of Rhodamine B. The composite photocatalyst showed improved degradation ability compared to pure g-C3N4, with a maximum removal rate of 99% for RhB. The enhanced photocatalytic activities of the products can be attributed to the suitable band structures and rich oxygen vacancies of the BiOCl/g-C3N4 composite for effective separation of photogenerated electron-hole pairs.

JOURNAL OF ELECTRONIC MATERIALS (2022)

Article Biochemistry & Molecular Biology

Photocatalytic performance and interaction mechanism of reverse micelle synthesized Cu-TiO2 nanomaterials towards levofloxacin under visible LED light

Kiran S. Varma et al.

Summary: The study investigated the degradation performance of Cu-TiO2 nanomaterials towards levofloxacin (LFX) antibiotic under a visible LED light source. Optimum photocatalytic degradation of 75.5% was achieved by 0.5 wt% Cu-TiO2 under 6 h. of visible light exposure. Formation of copper-LFX complexes in higher Cu-doped TiO2 samples, involving Cu2+, might have hindered the photocatalytic activity.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2022)

Article Engineering, Environmental

Morphology/facet-dependent photo-Fenton-like degradation of pharmaceuticals and personal care products over hematite nanocrystals

Abdul Hannan Asif et al.

Summary: This study investigates the relationship between morphology and photochemical performance of hematite nanocrystals. The plate-like sample shows the highest removal efficiency, and the reaction rate follows the order of cuboid/rhombohedral > plate-like > spheroid > rice-like.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

NH2-MIL-125(Ti) nanoparticles decorated over ZnO microrods: An efficient bifunctional material for degradation of levofloxacin and detection of Cu(II)

Manpreet Kaur et al.

Summary: The NH2-MIL-125(Ti)/ZnO heterostructure was developed as a dual functional platform for the degradation of levofloxacin and the detection of Cu(II) ions. The results showed that the heterostructure exhibited excellent photocatalytic performance and selective sensing properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Optimal synthesis of MoS2/Cu2O nanocomposite to enhance photocatalytic performance towards indigo carmine dye degradation

Pinki Sehrawat et al.

Summary: A nanocomposite of MoS2 nanosheets with Cu2O spheres was synthesized and used as a potent photocatalyst for indigo carmine (IC) dye degradation. The optimized heterostructure of Cu2O decorated on MoS2 exhibited a 45% enhancement in IC photodegradation efficiency compared to pristine MoS2. The nanocomposite also showed efficient removal of organic contaminants from wastewater.

APPLIED SURFACE SCIENCE (2022)

Article Materials Science, Ceramics

Insitu synthesis, characterization of Z-scheme g-C3N4/Bi2O3 as photocatalyst for degradation of azo dye, Amido black-10B under solar irradiation

Amandeep Kaur et al.

Summary: We report the synthesis of a Z-scheme g-C3N4/Bi2O3 photocatalyst using a facile in-situ approach, demonstrating its high efficiency in direct solar light-driven degradation of dyes. The obtained composite showed a degradation efficiency of 98.8% for the tested dye under optimized conditions and exhibited first-order reaction kinetics. The mechanism was investigated, revealing the significant contribution of O-2(-) and OH radicals in the photocatalytic process.

CERAMICS INTERNATIONAL (2022)

Article Green & Sustainable Science & Technology

Energy band reconstruction mechanism of Cl-doped Cu2O and photocatalytic degradation pathway for levofloxacin

Junkun Nie et al.

Summary: Cl-doped Cu2O microparticles were prepared and their microstructure, optical properties and degradation regularity were investigated. The results showed that Cl doping could increase the specific surface area and absorption efficiency of Cu2O microparticles. The photocatalytic degradation of levofloxacin might involve the attack of photogenerated holes and hydroxyl radicals, as well as the ring opening of the piperazine ring by oxidation and decarboxylation reactions.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Chemistry, Inorganic & Nuclear

Novel tablet-like Bi3TaO7/BiOCl 2D-2D heterostructure with heightened charge segregation for Visible-light-driven photocatalytic pollutants degradation

Aashna Nagar et al.

Summary: Industrial discharge poses a threat to the survival of living beings. This study investigated the fabrication of Bi3TaO7/BiOCl photocatalyst and its effectiveness in degrading pollutants. The composite material showed high efficiency in removing tetracycline and methylene blue in different pH environments.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

Article Chemistry, Physical

Polyaniline enwrapped CoFe2O4/g-CN ternary nanocomposite for adsorption driven photocatalytic degradation of explicitly diverse organic pollutants

Sneha Singh et al.

Summary: The present study investigates the potential of PANI@CoFe2O4/g-CN nanocomposites as photocatalysts for wastewater decontamination. The results show that the incorporation of PANI improves the adsorption capacity and enhances the rate of photocatalytic degradation of pollutants. Additionally, PANI improves the visible light absorption capacity and promotes the separation of photogenerated charge carriers.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Review Biochemistry & Molecular Biology

Current advances on the photocatalytic degradation of fluoroquinolones: photoreaction mechanism and environmental application

Luca Pretali et al.

Summary: In this brief review, the recent studies on the application of novel photocatalytic materials for the removal of fluoroquinolones from contaminated waters are summarized. The focus is on the properties of catalysts and their relation to the mechanistic aspects.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2022)

Article Environmental Sciences

Graphitic carbon nitride: a sustainable photocatalyst for organic pollutant degradation and antibacterial applications

Devina Rattan Paul et al.

Summary: Graphitic carbon nitride (GCN) has shown great potential in photocatalytic degradation of organic dyes and antibacterial activities, particularly in degrading cationic dyes efficiently. The synthesized GCN holds promise for effective remediation of organic pollutants and bacterial disinfection in wastewater treatment applications.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

Article Chemistry, Physical

Single-crystalline 2D BiOCl nanorods decorated with 2D MoS2 nanosheets for visible light-driven photocatalytic detoxification of organic and inorganic pollutants

Divya Monga et al.

Summary: The study successfully prepared BiOCl/MoS2 heterostructure via a simple and fast in-situ method, which demonstrated high degradation activity for various organic and inorganic pollutants under visible light. The catalyst showed high practical efficiency in treating industrial wastewater without any physico-chemical pretreatment.

FLATCHEM (2021)

Review Environmental Sciences

Simultaneous removal of organics and heavy metals from industrial wastewater: A review

Timothy O. Ajiboye et al.

Summary: The co-existence of heavy metals and organics in industrial effluents poses potential health risks and ecological harm, necessitating the simultaneous removal of these pollutants. Technologies such as adsorption, ion exchange, photo-catalysis, and coagulation have been used for this purpose, with their success dependent on water matrices and treatment media. This review critically examines the advantages, limitations, and mathematical modeling of these technologies for concurrent removal of organics and heavy metals in contaminated systems.

CHEMOSPHERE (2021)

Article Chemistry, Inorganic & Nuclear

Novel visible-light-induced BiOCl/g-C3N4 photocatalyst for efficient degradation of metronidazole

Yao Xu et al.

Summary: A new type of light stabilized nanocatalyst BiOCl/g-C3N4 was synthesized with superior morphology features and excellent photochemical catalytic performance, especially under visible light irradiation. The interaction between BiOCl and g-C3N4 was proven to enhance the separation of photo-generated holes and electrons, significantly improving the material's photostability and photocatalytic performance, as demonstrated through various experiments.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

Article Chemistry, Physical

A facile synthesis of high-crystalline g-C3N4 nanosheets with closed self-assembly strategy for enhanced photocatalytic H2 evolution

Jianxin Li et al.

Summary: Highly crystalline g-C3N4 nanosheets were synthesized with a simple self-assembly method, demonstrating improved photocatalytic activity compared to traditional g-C3N4, resulting in a 6-fold enhancement in hydrogen evolution.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Size-dependent effects of ZnO nanoparticles on the photocatalytic degradation of phenol in a water solution

E. Kusiak-Nejman et al.

Summary: The size of ZnO nanoparticles plays a significant role in the photocatalytic degradation of phenol under UV and visible light radiation. Nanoparticles with an average size of 71 nm showed the highest reaction rate for phenol degradation.

APPLIED SURFACE SCIENCE (2021)

Article Engineering, Environmental

Palladium and silver nanoparticles embedded on zinc oxide nanostars for photocatalytic degradation of pesticides and herbicides

Pitchaimani Veerakumar et al.

Summary: This study demonstrated efficient charge separation and migration at zinc oxide nanostars conjugated with noble metal nanoparticles, and their application in degrading carcinogenic pesticide and herbicides. The incorporation of noble metal nanoparticles on zinc oxide nanostar surface was successfully achieved using a microwave-hydrothermal method. The resulting nanocomposites exhibited excellent photocatalytic activity under visible light irradiation, with Pd@ZnONSt showing superior performance compared to other photocatalysts.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Biotechnology & Applied Microbiology

Fabrication of 3D porous peony flower-like β-Bi2O3/BiOCl heterostructure for synergistically boosting the visible-light-driven degradation of organic pollutants

Aashna Nagar et al.

Summary: A flower-like beta-Bi2O3/BiOCl binary composite with high degradation efficiency and reusability has been synthesized, featuring a narrow bandgap energy, large surface area, and mesoporous structure for degrading model dyes and insecticides efficiently.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2021)

Article Engineering, Environmental

Synergistic adsorption-photocatalytic degradation of different antibiotics in seawater by a porous g-C3N4/calcined-LDH and its application in synthetic mariculture wastewater

Yutang Yu et al.

Summary: The study successfully prepared a composite material M-CN/cLDH with excellent adsorption and photocatalytic removal capabilities, which can efficiently remove tetracycline antibiotics, especially OTC, from seawater. The material with a unique structure and rational composition has potential practical application value.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Chemistry, Multidisciplinary

Modulated BiOCl nanoplates with porous g-C3N4 nanosheets for photocatalytic degradation of color/colorless pollutants in natural sunlight

Aayushi Kundu et al.

Summary: A g-C3N4@BiOCl photocatalyst was studied for its preparation and application in photodegrading harmful pollutants. The 3:1 hybrid showed the best photocatalytic performance, with O-2(center dot-) identified as the major reactive species in photodegradation. The catalyst retained high efficiency after repeated use.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2021)

Review Chemistry, Analytical

Photocatalytic Degradation of Plastic Waste: A Mini Review

Qian Ying Lee et al.

Summary: Plastic waste poses an immediate threat to society by entering the food chain, and photocatalytic degradation processes offer a promising solution to accelerate the degradation rate. Research on new photocatalysts and processes for decomposing plastic waste is crucial in increasing recycling rates, especially in the current pandemic with a growing generation of plastic waste.

MICROMACHINES (2021)

Article Chemistry, Multidisciplinary

Construction of novel polyethylenimine-g-C3N4/BiOCl heterojunctions for the efficient photocatalytic degradation of nitro explosives

Jing Yan et al.

Summary: The study successfully constructed PEI-CN/BC heterojunctions that effectively degrade nitro explosive wastewater, improving photocatalytic performance by enhancing electron-hole separation. The results provide inspiration and alternatives for designing new efficient heterogeneous photocatalysts.

NEW JOURNAL OF CHEMISTRY (2021)

Article Nanoscience & Nanotechnology

Transition Metal Dichalcogenide-Silk Nanofibril Membrane for One-Step Water Purification and Precious Metal Recovery

Fengnian Zhao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Materials Science, Multidisciplinary

Hydrothermal synthesis of rGO-Bi2WO6 heterostructure for the photocatalytic degradation of levofloxacin

Mamta Arya et al.

OPTICAL MATERIALS (2020)

Article Materials Science, Ceramics

Novel g-C3N4 nanosheets/CDs/BiOCl photocatalysts with exceptional activity under visible light

Soheila Asadzadeh-Khaneghah et al.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2019)

Review Chemistry, Multidisciplinary

Pharmaceuticals of Emerging Concern in Aquatic Systems: Chemistry, Occurrence, Effects, and Removal Methods

Manvendra Patel et al.

CHEMICAL REVIEWS (2019)

Article Engineering, Environmental

Novel 3-D flower like Bi3O4Cl/BiOCl p-n heterojunction nanocomposite for the degradation of levofloxacin drug in aqueous phase

Girish Gupta et al.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2019)

Article Chemistry, Physical

Nanostructured cerium-doped ZnO for photocatalytic degradation of pharmaceuticals in aqueous solution

Rasheeda Al Abri et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2019)

Article Materials Science, Multidisciplinary

Synthesis of g-C3N4/N-doped CeO2 composite for photocatalytic degradation of an herbicide

Mohan Kumar Kesarla et al.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2019)

Article Electrochemistry

BiOCl Nanoplates Decorated on g-C3N4 for Enhanced Photocatalytic Activities

Yongkui Huang et al.

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE (2017)

Article Materials Science, Multidisciplinary

Photocatalytic degradation of levofloxacin in aqueous phase using Ag/AgBr/BiOBr microplates under visible light

Girish Gupta et al.

MATERIALS RESEARCH BULLETIN (2017)

Article Materials Science, Multidisciplinary

Hydrothermal synthesis of novel g-C3N4/BiOCl heterostructure nanodiscs for efficient visible light photodegradation of Rhodamine B

Lingjun Song et al.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2017)

Article Materials Science, Multidisciplinary

Ionic liquid-assisted synthesis and improved photocatalytic activity of p-n junction g-C3N4/BiOCl

Sheng Yin et al.

JOURNAL OF MATERIALS SCIENCE (2016)

Article Chemistry, Physical

Photolytic and photocatalytic degradation of fluoroquinolones in untreated river water under natural sunlight

Michela Sturini et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2012)

Article Chemistry, Physical

WO3/BiOCl, a novel heterojunction as visible light photocatalyst

Sajjad Shamaila et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2011)