Journal
ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 57, Issue 13, Pages 5137-5148Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.est.2c04151
Keywords
combustion aerosol; soot; black carbon; residential combustion; morphology; photochemical aging; aerosol optics; wood; brown coal
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In this study, the particle size dependency of the effective density (peff) was investigated for different types of particles from residential combustion and an aerosol standard burner. It was found that peff significantly increased due to photochemical aging, especially for larger soot agglomerates. The increase can be explained by the collapsing of chain-like agglomerates, filling of voids, and formation of secondary coating.
Effective density (peff) is an important property describing particle transportation in the atmosphere and in the human respiratory tract. In this study, the particle size dependency of peff was determined for fresh and photochemically aged particles from residential combustion of wood logs and brown coal, as well as from an aerosol standard (CAST) burner. peff increased considerably due to photochemical aging, especially for soot agglomerates larger than 100 nm in mobility diameter. The increase depends on the presence of condensable vapors and agglomerate size and can be explained by collapsing of chain-like agglomerates and filling of their voids and formation of secondary coating. The measured and modeled particle optical properties suggest that while light absorption, scattering, and the single-scattering albedo of soot particle increase during photochemical processing, their radiative forcing remains positive until the amount of nonabsorbing coating exceeds approximately 90% of the particle mass.
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