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Recent advancements in MXene-based nanocomposites as photocatalysts for hazardous pollutant degradation-A review

Journal

ENVIRONMENTAL RESEARCH
Volume 233, Issue -, Pages -

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.envres.2023.116459

Keywords

MXene; MXene-based composites; Synthesis methods; Photocatalyst; Stability; Pollutant degradation

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The rapid industrialization and urbanization have led to an increasing demand for energy and a severe environmental crisis. In response, 2-dimensional (2D) nanomaterials, particularly MXenes, have been developed as a solution to meet future energy requirements and address environmental issues. MXenes exhibit unique properties, such as a large surface area, strong conductivity, fascinating photophysical properties, high mechanical properties, stability in water, high hydrophilicity, biocompatibility, ease of functionalization, and excellent thermal properties. MXenes have shown potential in water desalination, energy storage devices, hydrogen production, sensors, and wastewater treatment. This article reviews the synthesis of MXene and MXene-based nanocomposites, their photocatalytic actions against toxic pollutants, and the efforts made to enhance their photocatalytic activity.
The recent expeditious industrialization and urbanization showcase the increasing need for renewable and nonrenewable energy and the severe environmental crisis. In this regard, numerous 2-dimensional (2D) nanomaterials have been developed as a facile approach to meet the futuristic energy essentials and to resolve the crisis. In contrast, the newly explored 2D MXenes (transition metal carbide/nitrides/carbonitride) have been employed as an intriguing material for various environmental applications. This development is accredited to their unique properties, which include a vast surface area, strong electrical conductivity, fascinating photophysical properties, high mechanical properties, stability in an aqueous medium, high hydrophilicity, biocompatibility, ease of functionalization, and excellent thermal properties. MXenes act as a potential candidate in water desalination, energy storage devices such as electrodes of Li-ion batteries and pseudo capacitors, hydrogen production, sensors, and wastewater treatment. This review article deliberates the synthesis of MXene and nanocomposites of MXene and their photo-catalytic actions against various toxic pollutants such as organic dyes and heavy metals in wastewater. This review also precises the various preparation methods of MXene-based photocatalyst and the enhanced photocatalytic activity of MXene and MXene-based nanocomposites in wastewater treatment. Also, it details the attempts made to improve the photocatalytic activity of MXene-based nanocomposites in terms of their structural compositions. In addition, the merits and demerits of the MXenebased photocatalysts are deliberated, which may pave the way for future research in this arena.

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