4.6 Article

Environmental factors influencing DDT-DDE spatial distribution in an agricultural drainage system determined by using machine learning techniques

Journal

ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
Volume -, Issue -, Pages -

Publisher

SPRINGER
DOI: 10.1007/s10653-023-01486-y

Keywords

DDT; DDE; Spatial distribution; Soil texture; Hydrology; Random forest; Mutual information

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This study investigates the presence and persistence of DDT-DDE in a Mediterranean coastal plain and analyzes the environmental factors that influence its spatial distribution in watercourses. Machine learning techniques were used to classify DDT-DDE concentration levels based on other environmental variables. The results show that distance to drain canals, soil electrical conductivity, and soil sand texture fraction are the most informative variables for predicting DDT-DDE water concentration clusters.
The presence and persistence of pesticides in the environment are environmental problems of great concern due to the health implications for humans and wildlife. The persistence of DDT-DDE in a Mediterranean coastal plain where pesticides were widely used and were banned decades ago is the aim of this study. Different sources of analytical information from water and soil analysis and topography and geographical variables were combined with the purpose of analyzing which environmental factors are more likely to condition the spatial distribution of DDT-DDE in the drainage watercourses of the area. An approach combining machine learning techniques, such as Random Forest and Mutual Information (MI), for classifying DDT-DDE concentration levels based on other environmental predictive variables was applied. In addition, classification procedure was iteratively performed with different training/validation partitions in order to extract the most informative parameters denoted by the highest MI scores and larger accuracy assessment metrics. Distance to drain canals, soil electrical conductivity, and soil sand texture fraction were the most informative environmental variables for predicting DDT-DDE water concentration clusters.

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