One-Dimensional RuO2-Nitrogen-Doped Carbon Composite for Energy Storage Application in an Alkaline Medium

One-dimensional (1D) electrode materials have been the most promising material for supercapacitors because of their unique features, such as 1D morphology with large surface area, high mechanical rigidity, excellent cyclic stability, and great electrical conductivity. Herein, we demonstrate a one-dimensional RuO2-N-doped carbon (1D-RuO2/C) composite, synthesized by a facile thermal method, for supercapacitor application. The 1D-RuO2/C composite delivers a specific capacitance (Cs) of 671 F/g under a current of 5 A/g with extraordinary capacitance retention of 93.46% after 5000 cycles. The asymmetric supercapacitor (ASC) device (1D-RuO2/C//AC) was constructed using 1D-RuO2/C as the positive electrode material and activated carbon as the negative electrode material. The 1D-RuO2/C//AC device shows a Cs value of 53 F/g under 1 A/g current and delivers a power density (PD) of 751.66 W kg-1 at 16.71 Wh kg-1 energy density (ED). The ASC maintains approximately 98.65% of its initial value at 10 A/g discharge current. The high electrochemical activity of the 1D-RuO2/C composite is primarily due to the 1D morphology of RuO2, high surface area, synergistic interaction between RuO2 and carbon support, etc. We hope that this 1D-RuO2/C composite will find its application in energy storage systems.

Automated summary

In this study, a one-dimensional RuO2-N-doped carbon (1D-RuO2/C) composite is synthesized and demonstrated for supercapacitor application. The 1D-RuO2/C composite exhibits a specific capacitance of 671 F/g and retains 93.46% of its capacitance after 5000 cycles at 5 A/g current. An asymmetric supercapacitor (ASC) device, constructed using 1D-RuO2/C as the positive electrode material, shows a specific capacitance of 53 F/g, a power density of 751.66 W kg-1, and an energy density of 16.71 Wh kg-1. The ASC maintains approximately 98.65% of its initial value at 10 A/g discharge current. The high electrochemical activity of the 1D-RuO2/C composite is attributed to its 1D morphology, high surface area, and synergistic interaction between RuO2 and carbon support. The researchers hope that this composite material will find applications in energy storage systems.