Journal
DIAMOND AND RELATED MATERIALS
Volume 135, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2023.109815
Keywords
Black cumin; Activated carbon; Characterization; Sorption; Supercapacitor
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In this study, solid residues (BR) from the black cumin processing industry were converted into high surface area mesoporous activated carbon (AC) using a K2CO3 assisted carbonization method. The optimal AC (BRAC) achieved the highest BET surface area, total pore volume, and mean pore diameter. It also exhibited high adsorption performance for model water pollutants and showed excellent electrochemical capacitor performance.
In this study, solid residues (BR) from the black cumin (Nigella sativa) processing industry, an abundant and sustainable raw material, were converted into high surface area mesoporous activated carbon (AC) under op-timum production conditions using a single-stage K2CO3 assisted carbonization method. The optimal AC (BRAC) which had the highest BET surface area (2211 m2/g), total pore volume (1.262 cm3/g), and mean pore diameter (2.8 nm) was achieved in the conditions of a K2CO3 impregnation ratio of 1:1, a carbonization temperature of 900 degrees C, and a carbonization period of 1 h. To test its adsorption performance from the aqueous phase, methylene blue dye, oxytetracycline antibiotic, and lead metal ions were selected as model water pollutants and found to be 714.3, 833.3, and 500.0 mg/g, respectively, at 25 degrees C Also, the electrode made of BRAC showed electrochemical capacitor performance with a high gravimetric capacitance (210 F/g) and cyclic stability (95 %).
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