Journal
ADVANCED MATERIALS
Volume 27, Issue 33, Pages 4918-4923Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201501489
Keywords
intermediate complex; mixed-organic-cation; perovskite; phase-pure; solar cells
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Funding
- Core Research for Evolutional Science and Technology (CREST) of the Japan Science and Technology Agency
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A high-quality mixed-organic-cation perovskite (MA)(x)(FA)(1-x)PbI3 is prepared from a phase-pure non-stoichiometric intermediate complex (FAI)(1-x)-PbI2. The phase-pure (FAI)(1-x)-PbI2 probably facilitates homogenous nucleation and modulates the growth kinetics during the crystallization of (MA)(x)(FA)(1-x)PbI3. This strategy can be expected to pave the way for the development of mixed-organic-cation perovskite solar cells.
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