4.4 Article

Modification on crystallization behavior and mechanical properties of polylactide by the addition of polyamide elastomer

Journal

COLLOID AND POLYMER SCIENCE
Volume 301, Issue 8, Pages 967-977

Publisher

SPRINGER
DOI: 10.1007/s00396-023-05117-x

Keywords

Polylactide; Polyamide elastomer; Phase morphology; Crystallization behavior; Mechanical properties

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The phase morphology, crystallization behavior, and mechanical properties of PLA modified by PAE were investigated. PAE was found to be uniformly dispersed in the PLA matrix, forming a sea-island morphology. The addition of PAE promoted the crystallization of PLA and improved its elongation at break and impact strength. The sample with 20 wt% PAE showed the best rigidity-toughness balance and ductile failure, and the toughening mechanism was proposed based on the deformation of the impact fracture surfaces.
The phase morphology, crystallization behavior, and mechanical properties of polylactide (PLA) modified by polyamide elastomer (PAE) have been systematically investigated. SEM images showed that PAE was homogeneously dispersed in the PLA matrix forming a sea-island morphology. The dimension of PAE domains increased slightly with its content and still remained smaller than 3 mu m even at 40 wt% due to the partial compatibility of PLA and PAE. PAE had some nucleation effect on PLA and promoted the crystallization of PLA to a certain extent. The crystallization kinetics and crystalline morphology, especially the nucleation and growth of PLA crystals, were compared in detail between pure PLA and PLA/PAE blends. The elongation at break and impact strength of PLA were considerably improved by PAE. The sample PAE20 exhibited the best rigidity-toughness balance showing ductile failure. The toughening mechanism was proposed based on the deformation of the impact fracture surfaces.

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