4.8 Article

Enhanced Performance in Fluorene-Free Organometal Halide Perovskite Light-Emitting Diodes using Tunable, Low Electron Affinity Oxide Electron Injectors

Journal

ADVANCED MATERIALS
Volume 27, Issue 8, Pages 1414-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405044

Keywords

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Funding

  1. Cambridge Commonwealth
  2. European and International Trusts
  3. Rutherford Foundation of New Zealand
  4. A*STAR
  5. Girton College Cambridge
  6. Gates Cambridge Scholarship
  7. EPSRC [EP/G060738/1]
  8. ERC [ERC-2009-adG 247276]
  9. Cambridge Display Technology
  10. Royal Society
  11. Engineering and Physical Sciences Research Council [EP/G060738/1] Funding Source: researchfish
  12. EPSRC [EP/G060738/1] Funding Source: UKRI

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Fluorene-free perovskite light-emitting diodes (LEDs) with low turn-on voltages, higher luminance and sharp, color-pure electroluminescence are obtained by replacing the F8 electron injector with ZnO, which is directly deposited onto the CH3NH3PbBr3 perovskite using spatial atmospheric atomic layer deposition. The electron injection barrier can also be reduced by decreasing the ZnO electron affinity through Mg incorporation, leading to lower turn-on voltages.

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