Photo-electrocatalytic based removal of acetaminophen: Application of visible light driven heterojunction based BiVO4/BiOI photoanode

The presence of organic micro-pollutants (OMPs) in wastewater treatment effluents is becoming a major threat to the water safety for aquatic and human health. Photo-electrocatalytic based advanced oxidation process (AOP) is one of the emerging and effective techniques to degrade OMPs through oxidative mechanism. This study investigated the application of heterojunction based BiVO4/BiOI photoanode for acetaminophen (40 mu g L-1) removal in demineralized water. Photoanodes were fabricated by electrodeposition of BiVO4 and BiOI photo-catalytic layers. Optical (UV-vis diffusive reflectance spectroscopy), structural (XRD, SEM, EDX) and opto-electronic (IPCE) characterization confirmed the successful formation of heterojunction for enhanced charge separation efficiency. The heterojunction photoanode showed incident photon to current conversion efficiency of 16% (lambda max = 390 nm) at an external voltage of 1 V under AM 1.5 standard illumination. The application of the BiVO4/BiOI photoanode in the removal of acetaminophen at 1 V (external bias) vs Ag/AgCl under simulated sunlight showed 87% removal efficiency within the first 120 min compared to 66% removal efficiency of the BiVO4 photoanode. Similarly, combining BiVO4 and BiOI exhibited 57% increase in first order removal rate coefficient compared to BiVO4. The photoanodes also showed moderate stability and reusability by showing 26% decrease in overall degradation efficiency after three cycles of each 5 h experiment. The results obtained in this study can be considered as a stepping stone towards the effective removal of acetaminophen as an OMP present in wastewater.

Automated summary

The presence of organic micro-pollutants (OMPs) in wastewater treatment effluents poses a significant threat to water safety. A study investigated the application of BiVO4/BiOI heterojunction photoanode for acetaminophen removal in demineralized water. The heterojunction photoanode showed improved charge separation efficiency and exhibited higher removal efficiency compared to BiVO4 photoanode. These results provide valuable insights for the effective removal of acetaminophen, an OMP, from wastewater.