4.6 Article

Electrophilic Si-H Activation by Acetonitrilo Benzo[h]quinoline Iridacycles: Influence of Electronic Effects in Catalysis

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis

Bogdan Marciniec et al.

Summary: This Review summarizes the developments in inorganometallic catalysis over the last 15 years, highlighting the importance of inorganometallics in the synthesis of metalloid compounds and advanced organic synthesis.

CHEMICAL REVIEWS (2022)

Article Chemistry, Multidisciplinary

Recent advances in ruthenium-catalyzed hydrosilylation of unsaturated compounds: Applications and mechanistic studies

Amrutha P. Thankachan et al.

Summary: Organosilanes play a significant role in synthetic organic chemistry, serving as intermediates for the synthesis of natural products, elastomers, and resins, as well as effective coupling partners in cross-coupling reactions. Hydrosilylation, using transition metal catalysts such as Ru-based complexes, has emerged as the most efficient method for preparing organosilicon compounds and finds broad applications in material chemistry and organic synthesis.

RESULTS IN CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different

Pablo Rios et al.

Summary: This Perspective discusses the activation and cleavage of Si-H and B-H bonds by transition metal complexes in an electrophilic manner, comparing their reactivity with boron/aluminium Lewis acids and proposing mechanisms involving electrophilic reaction pathways.

CHEMICAL SCIENCE (2022)

Review Chemistry, Multidisciplinary

Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts

Hendrik F. T. Klare et al.

Summary: The history of silyl cations had a dramatic beginning, as they were once considered impossible to isolate in the condensed phase. However, their actual characterization in solution and solid state changed this perception, leading to wide acceptance and promising applications in synthetic chemistry. Silyl cations are known for their enormous electrophilicity and reactivity, making them key compounds in various chemical reactions.

CHEMICAL REVIEWS (2021)

Review Chemistry, Multidisciplinary

σ-H-H, σ-C-H, and σ-Si-H Bond Activation Catalyzed by Metal Nanoparticles

Juan M. Asensio et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

New Way for Probing Bond Strength

Johanna Klein et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Mercury 4.0: from visualization to analysis, design and prediction

Clare F. Macrae et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2020)

Article Chemistry, Physical

A generally applicable atomic-charge dependent London dispersion correction

Eike Caldeweyher et al.

JOURNAL OF CHEMICAL PHYSICS (2019)

Article Chemistry, Multidisciplinary

Dative and Electron-Sharing Bonding in Transition Metal Compounds

Paul Jerabek et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2019)

Article Chemistry, Applied

Synthesis of 5-Substituted Benzo[h]quinoline Derivatives via Reactions Involving C(sp2)-Br Bond Activation

Bartosz Orwat et al.

ADVANCED SYNTHESIS & CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Entrapment of THF-Stabilized Iridacyclic Ir-III Silylenes from Double H-Si Bond Activation and H-2 Elimination

Dang Ho Binh et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Chemistry, Multidisciplinary

Is the R3Si Moiety in Metal-Silyl Complexes a Z ligand? AnAnswer from the Interaction Energy

Dang Ho Binh et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Article Chemistry, Physical

On Atoms-in-Molecules Energies from Kohn-Sham Calculations

Vincent Tognetti et al.

CHEMPHYSCHEM (2017)

Review Chemistry, Multidisciplinary

Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations

Mark C. Lipke et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Catalytic reduction of amides to amines by electrophilic phosphonium cations via FLP hydrosilylation

Alessandra Augurusa et al.

CHEMICAL COMMUNICATIONS (2016)

Review Chemistry, Multidisciplinary

Thermodynamic Hydricity of Transition Metal Hydrides

Eric S. Wiedner et al.

CHEMICAL REVIEWS (2016)

Review Chemistry, Multidisciplinary

Reactive p-block cations stabilized by weakly coordinating anions

Tobias A. Engesser et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Inorganic & Nuclear

Evidence of a Donor-Acceptor (Ir-H)→SiR3 Interaction in a Trapped Ir(III) Silane Catalytic Intermediate

Mustapha Hamdaoui et al.

ORGANOMETALLICS (2016)

Article Chemistry, Multidisciplinary

Chemoselective nitro reduction and hydroamination using a single iron catalyst

Kailong Zhu et al.

CHEMICAL SCIENCE (2016)

Article Chemistry, Physical

Platinum Catalysis Revisited-Unraveling Principles of Catalytic Olefin Hydrosilylation

Teresa K. Meister et al.

ACS CATALYSIS (2016)

Article Chemistry, Organic

Boron-Catalyzed Silylative Reduction of Nitriles in Accessing Primary Amines and Imines

Narasimhulu Gandhamsetty et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Inorganic & Nuclear

Quantitative Assessment of the Lewis Acidity of Silylium Ions

Henning Grossekappenberg et al.

ORGANOMETALLICS (2015)

Article Chemistry, Multidisciplinary

Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex

Toni T. Metsaenen et al.

CHEMICAL SCIENCE (2015)

Article Chemistry, Physical

Efficient hydrosilylation of imines using catalysts based on iridium(III) metallacycles

Y. Corre et al.

CATALYSIS SCIENCE & TECHNOLOGY (2015)

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

Kinetics and Thermodynamics of H-/H•/H+ Transfer from a Rhodium(III) Hydride

Yue Hu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart's Cationic Iridium(III) Pincer Complex

Toni T. Metsaenen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Inorganic & Nuclear

Structure and Solution Reactivity of (Triethylsilylium)triethylsilane Cations

Samantha J. Connelly et al.

ORGANOMETALLICS (2013)

Article Chemistry, Multidisciplinary

Silyl Cation Mediated Conversion of CO2 into Benzoic Acid, Formic Acid, and Methanol

Andre Schaefer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Applied

Kinetic Understanding Using NMR Reaction Profiling

Flavien Susanne et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2012)

Editorial Material Chemistry, Physical

Turning Over Definitions in Catalytic Cycles

Sebastian Kozuch et al.

ACS CATALYSIS (2012)

Article Chemistry, Multidisciplinary

The ORCA program system

Frank Neese

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2012)

Article Chemistry, Organic

Bond Ellipticity as a Measure of Electron Delocalization in Structure and Reactivity

Carlos Silva Lopez et al.

CURRENT ORGANIC CHEMISTRY (2011)

Article Chemistry, Physical

NCIPLOT: A Program for Plotting Noncovalent Interaction Regions

Julia Contreras-Garcia et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2011)

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Nonhydride Mechanism of Metal-Catalyzed Hydrosilylation

Oleg G. Shirobokov et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Inorganic & Nuclear

Triethylsilyl Perfluoro-Tetraphenylborate, [Et3Si+][F20-BPh4-], a Widely Used Nonexistent Compound

Matthew Nava et al.

ORGANOMETALLICS (2011)

Article Chemistry, Organic

Highly Chemo- and Regioselective Reduction of Aromatic Nitro Compounds Using the System Silane/Oxo-Rhenium Complexes

Rita G. de Noronha et al.

JOURNAL OF ORGANIC CHEMISTRY (2009)

Article Chemistry, Physical

A molecular energy decomposition scheme for atoms in molecules

E Francisco et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2006)

Article Chemistry, Physical

Interacting quantum atoms:: A correlated energy decomposition scheme based on the Quantum Theory of Atoms in Molecules

MA Blanco et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2005)

Review Chemistry, Multidisciplinary

Chemistry with ADF

G te Velde et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2001)