4.4 Article

Dye-sensitized solar cells using nickel-palladium-reduced graphene oxide cathode: effect of deposition temperature

Journal

CHEMICAL PAPERS
Volume 77, Issue 8, Pages 4625-4632

Publisher

SPRINGER INT PUBL AG
DOI: 10.1007/s11696-023-02812-5

Keywords

Deposition temperature; Cathode; Dye-sensitized solar cells; Nickel; Palladium

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Preparation of NiPd-rGO cathode via LPD technique and its effect on the performance of DSSC have been studied. The deposition temperature of NiPd has been found to significantly influence the morphology, elemental composition, and optical transmittance of the samples. The DSSC device using NiPd-rGO cathode prepared at a deposition temperature of 60 degrees C shows the highest PCE of 3.07% due to its lowest R-ct and highest R-cr.
Preparation parameter of cathode for DSSC is crucial in determining the performance of the device. In this work, nickel-palladium-reduced graphene oxide (NiPd-rGO) cathode has successfully been prepared via liquid-phase deposition (LPD) technique. The effect of NiPd deposition temperature of the properties of NiPd-rGO sample has been studied. The influence of the deposition temperature on the photovoltaic parameters of the DSSC using NiPd-rGO cathodes has also been investigated. The thickness of the sample is found to increase with the deposition temperature. The morphology, elemental composition and optical transmittance are significantly affected by the deposition temperature. The device using NiPd-rGO cathode prepared at NiPd deposition temperature of 60 degrees C produces the highest PCE of 3.07%. This is due to this device owns the lowest R-ct and highest R-cr.

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