4.7 Article

Abrasion-resistant superhydrophilic objects with anisotropic water transport capacities prepared by a selective laser sintering 3D printing strategy

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 464, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.142778

Keywords

SLS 3D printing; Superhydrophilic object; Anisotropic; Abrasion-resistant; Water transport; Solar steam generation

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This study presents the one-step construction of abrasion-resistant superhydrophilic objects with anisotropic water transport capacities using selective laser sintering. The inserted hydrophilic glass beads and thermoplastic phenol-formaldehyde resin grains form long capillary channels, enabling anisotropic water transport on different surfaces. The superhydrophilic materials also exhibit abrasion resistance and excellent anti-gravity water transport ability.
Liquid directional manipulation has been widely used in the fields of microfluidic, microreactor, liquid separation and collection, sewage treatment. Most studies based on the construction of gradient structures on the substrate surface realized liquid directional transportation, but their fragile surfaces are vulnerable to external forces and can only transport thin water film according to the array thickness. Here, we report that abrasionresistant superhydrophilic objects with anisotropic water transport capacities can be one-step constructed by selective laser sintering (SLS) the composites of hydrophilic glass beads (GBs) and thermoplastic phenol-formaldehyde resin (PF) grains. The long interlayer micro-slits between the adjacent printing layers cooperated with the inserted hydrophilic GBs formed long capillary channels, resulting in anisotropic water transport abilities on different printing surfaces. In addition, the abrasion-resistant ability endowed superhydrophilic mechanical stability. Furthermore, water could climb about similar to 26 cm along the horizontal printed sample, showing excellent anti-gravity water transport ability. Finally, we demonstrated that the printed evaporators with diverse salt-resistant structures not only maintain long-term salt resistance, but also possess high evaporation efficiency. The superhydrophilic materials proposed in this study will lead the design and preparation of liquid directional transport materials and provide advanced inspiration for 3D printing functional materials.

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