4.7 Article

Understanding non-stochiometric deposition of multi-principal elemental NiCoCr thin films

Journal

APPLIED SURFACE SCIENCE
Volume 623, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2023.157011

Keywords

Pulsed laser deposition; Multi-principal elemental alloys; NiCoCr; Thin films; Electron microscopy; X-ray absorption spectroscopy

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Multi-principal elemental NiCoCr thin films have compositional flexibility and can be used as thermal barrier, corrosion-resistant coatings, and functional energy materials. This study investigates the non-stochiometric formation behavior of NiCoCr thin films using pulsed laser deposition. The laser fluence has an effect on the constituent element compositions, and the films show partially oxidized with Cr oxidation contributing the most.
Multi-principal elemental NiCoCr thin films with compositional flexibility have potential applications as a thermal barrier, corrosion-resistant coatings, and functional energy materials. In this study, the non-stochiometric multi-principal element alloy thin film formation behavior from an equiatomic ablation target of NiCoCr using pulsed laser deposition has been reported. Here, the effect of varying laser fluence on compositions of constituent elements in the NiCoCr thin films is systematically investigated. The increase in laser fluence typically increases the likelihood of acquiring undesirable particulates in thin films. Therefore, to maintain the film quality the laser fluences are adjusted within the range of 1.3-3.3 J center dot cm(-2), while the film thicknesses are kept constant at similar to 30 nm. Results show that the constituent elements are well-distributed in the formed NiCoCr thin films, however, having average atomic percentages of Ni and Cr twice as high as Co irrespective of the equiatomic composition of individual elements in the ablation target. This stochiometric alteration in the as-deposited thin films is governed by the rate of ablation and subsequent evaporation of each element, which is facilitated by the optical properties and vapor pressure of individual constituent elements. Additionally, electron energy-loss spectroscopy and x-ray absorption spectroscopy analysis reveal that the thin films have partially oxidized, with the Cr oxidation contributing the most to the O-K edge in comparison to Ni and Co. This study presents a laser-assisted pathway for fabricating compositionally flexible NiCoCr thin films and develops an understanding of the non-equilibrium laser-material interactions and how the intrinsic properties of constituent elements affect the stoichiometric flow of materials from the target to the final film deposition.

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