Interfacial oxidation and boundary amorphization deposition mechanisms of GaN powder on metallic substrate by low-pressure cold spraying

Understanding powder adhesion mechanism in cold spray is primordial to control the coating formation. Pre-vious studies have suggested that metallic coatings are governed by metallurgical bonding, but no consensus has been established regarding the bonding mechanisms of ceramic particles. In this study, the deposition mecha-nism of agglomerated gallium nitride (GaN) particles cold sprayed on stainless steel substrates was investigated. The evolution of the oxide layer thickness and coating/particle microstructures were analyzed by X-ray photo-electron spectroscopy and transmission electron microscopy. The results revealed that although mechanical interlocking and coating thickness were enhanced by the substrate surface roughness, grain refinement was not the key factor for the brittle particle deposition, considering the diameter of the nano-sized particles. Instead, a new interfacial oxide layer was formed because of the destruction and removal of native oxide films upon impact. Local heteroepitaxy, which occurred near the interface of the newly formed gallium oxide, enhanced the coating formation. Compared with the GaN feedstock, the coating exhibited boundary amorphization and a high dislocation density induced by the high strain rate. Thus, this study proposed considerable insight into the formation mechanisms of cold-sprayed GaN coatings, which can support a more expanded range of ceramic/ metal combinations in the future.

Automated summary

Understanding the deposition mechanism of cold-sprayed GaN coatings on stainless steel substrates is important for controlling coating formation. This study investigated the formation mechanisms by analyzing the oxide layer thickness and microstructures using X-ray photo-electron spectroscopy and transmission electron microscopy. The results showed that the formation of a new interfacial oxide layer and local heteroepitaxy near the newly formed gallium oxide interface enhanced the coating formation. The study proposed insights into the formation mechanisms of cold-sprayed GaN coatings, which can support a wider range of ceramic/metal combinations in the future.