Boosting ethanol oxidation by NiOOH-CuO nano-heterostructure for energy-saving hydrogen production and biomass upgrading

Substituting the anodic oxygen evolution reaction in water electrolysis with a thermodynamically more favorable ethanol oxidation reaction (EOR) provides a promising route for simultaneous biomass upgrading and energysaving hydrogen production. Herein, we synthesize a NiOOH-CuO nano-heterostructure anchored on a threedimensional conductive Cu foam, which exhibits remarkable EOR performance, surpassing all the state-of-theart 3d transition-metal-based EOR electrocatalysts. Density functional theory reveals that the coupling between CuO and NiOOH by charge redistribution at the interface is critical, synergistically reducing the EOR energy barriers into an energetically favorable pathway. Conclusively, the hybrid water electrolysis cell using our catalyst as the anode (1) requires only a low cell voltage for H2 generation at the cathode and only liquid chemical production of acetate at the anode, and (2) shows a high ethanol conversion rate to acetate, which can readily be separated from the aqueous electrolyte by subsequent acidification and extraction processes.

Automated summary

Substituting the anodic oxygen evolution reaction with a thermodynamically more favorable ethanol oxidation reaction in water electrolysis provides a promising route for simultaneous biomass upgrading and energy-saving hydrogen production. The synthesis of a NiOOH-CuO nano-heterostructure anchored on a three-dimensional conductive Cu foam exhibits remarkable ethanol oxidation reaction performance. The hybrid water electrolysis cell using this catalyst as the anode shows low cell voltage for hydrogen generation at the cathode and high ethanol conversion rate to acetate, which can be easily separated.