Complex films formed on Al alloy surface via vapor phase assembly of benzotriazole and dodecyltrimethoxysilane

PurposeThe purpose of this paper is to study the effect of vapor assembly sequence and assembly temperature on the corrosion protection of the complex silane films Al alloy. The performance and application range of silane films are enhanced. Design/methodology/approachThe complex silane films were successfully prepared on the surface of aluminum alloy using via vapor phase assembly of 1,2,3-benzotriazole (BTA) and dodecyltrimethoxysilanes (DTMS). The protection of the assembly films against corrosion of Al alloy is investigated by the electrochemical measurements and the alkaline solution accelerated corrosion test. Thickness and hydrophobicity of the complex films are studied using ellipsometric spectroscopy and contact angle tests. FindingsIt shows that the anti-corrosion ability of the complex films is overall superior to that of the single-component assembled films. DTMS-BTA films have larger thickness and best anti-corrosion ability. The alkyl chains in DTMS have better compatibility with BTA molecules. The rigid BTA molecule can permeate into the long alkyl chain of DTMS as fillers and improve the barrier properties of the complex films. Originality/valueIn this paper, a green and efficient method of vapor phase assembly is proposed to rust prevention during manufacture of Al alloy workpiece.

Automated summary

The effect of vapor assembly sequence and assembly temperature on the corrosion protection of complex silane films on Al alloy was studied. The performance and application range of silane films were improved. Electrochemical measurements and alkaline solution accelerated corrosion test were used to investigate the corrosion protection of the assembly films. Thickness and hydrophobicity of the complex films were studied using ellipsometric spectroscopy and contact angle tests.