Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 50, Pages 16266-16273Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05712
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Funding
- University of Pennsylvania
- American Chemical Society [56128-ND3]
- U.S. National Science Foundation [OCI-1053575]
- NSF LRSM Research Experiences for Undergraduates (REU) program at UPenn [DMR-1359351]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1359351] Funding Source: National Science Foundation
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The hexachlorocerate(III) anion, [(CeCl6)-Cl-III](3-), was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction potential of -3.45 V versus Cp2Fe0/+. Despite a short lifetime of 22.1(1) ns, the anion exhibited a photoluminescence quantum yield of 0.61(4) and fast quenching kinetics toward organohalogens allowing for its application in the photocatalytic reduction of aryl chloride substrates.
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