Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202305280
Keywords
Agostic; pi-Allyl; Cyclopropyl; Gold; Rearrangement
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The possibility of ring-opening of Au-III sigma-cyclopropyl complexes to form p-allyl complexes was investigated. The transformation was observed in (P,C)-cyclometalated complexes at -50 degrees C within hours and was later generalized to other ancillary ligands. Density Functional Theory (DFT) calculations revealed the mechanism of the transformation to be a disrotatory electrocyclic ring-opening. The existence of C-C agostic interactions at Au-III in cationic sigma-cyclopropyl complexes was supported by careful analysis of their structure and bonding.
The possibility for Au-III sigma-cyclopropyl complexes to undergo ring-opening and give p-allyl complexes was interrogated. The transformation was first evidenced within (P,C)-cyclometalated complexes, it occurs within hours at -50 degrees C. It was then generalized to other ancillary ligands. With (N,C)-cyclometalated complexes, the rearrangement occurs at room temperature while it proceeds already at -80 degrees C with a dicationic (P,N)-chelated complex. Density Functional Theory (DFT) calculations shed light on the mechanism of the transformation, a disrotatory electrocyclic ring-opening. Intrinsic Bond Orbital (IBO) analysis along the reaction profile shows the cleavage of the distal sigma(CC) bond to give a pi-bonded allyl moiety. Careful inspection of the structure and bonding of cationic sigma-cyclopropyl complexes support the possible existence of C-C agostic interactions at Au-III.
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