Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 9, Pages 2985-2988Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b01376
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Funding
- Welch Foundation [AX-1788]
- NSF [CHE-1455061]
- Max and Minnie Tomerlin Voelcker Fund
- UTSA
- NIMHD [G12MD007591]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1455061] Funding Source: National Science Foundation
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We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters and carried out on gram scale as well as under flow conditions.
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