Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202300640
Keywords
Hydrothermal Method; Polymorphs; Semiconductor; Sn3O4; Tin Oxide
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An unexplored tin oxide crystal phase (Sn3O4) was synthesized using a convenient hydrothermal method. By tuning the often-neglected parameters, a new X-ray diffraction pattern was discovered. Through various characterization techniques, this novel material was identified as orthorhombic mixed-valence tin oxide (Sn2SnO4)-Sn-II-O-IV, which is a new polymorph of Sn3O4. It has a smaller band gap (2.0 eV) and higher visible light absorption. This study is expected to improve hydrothermal synthesis and facilitate the discovery of new oxide materials.
An unexplored tin oxide crystal phase (Sn3O4) was experimentally synthesized via a facile hydrothermal method. After tuning the often-neglected parameters for the hydrothermal synthesis, namely the degree of filling of the precursor solution and the gas composition in the reactor head space, an unreported X-ray diffraction pattern was discovered. Through various characterization studies, such as Rietveld analysis, energy dispersive X-ray spectroscopy, and first-principles calculations, this novel material was characterized as orthorhombic mixed-valence tin oxide with the composition (Sn2SnO4)-Sn-II-O-IV. This orthorhombic tin oxide is a new polymorph of Sn3O4, which differs from the reported conventional monoclinic structure. Computational and experimental analyses showed that orthorhombic Sn3O4 has a smaller band gap (2.0 eV), enabling greater absorption of visible light. This study is expected to improve the accuracy of hydrothermal synthesis and aid the discovery of new oxide materials.
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