4.8 Review

In Situ X-ray Absorption Spectroscopy of Metal/Nitrogen-doped Carbons in Oxygen Electrocatalysis

Journal

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202219188

Keywords

Active Sites; In Situ XAS; M-N-C Catalysts; Oxygen Electrocatalysis; Structural Evolution

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Metal/nitrogen-doped carbons (M-N-C) are attractive oxygen electrocatalysts with low cost, tunable activity, and well-dispersed morphologies. In situ X-ray absorption spectroscopy (XAS) is a powerful characterization technique for studying the structure and properties of M-N-C catalysts under reaction conditions. This review provides an overview of XAS fundamentals and comprehensively discusses the setup, applications, and challenges of in situ XAS in catalysis. The review also highlights the investigation of active sites and structural evolution of M-N-C catalysts during oxygen electrocatalysis.
Metal/nitrogen-doped carbons (M-N-C) are promising candidates as oxygen electrocatalysts due to their low cost, tunable catalytic activity and selectivity, and well-dispersed morphologies. To improve the electrocatalytic performance of such systems, it is critical to gain a detailed understanding of their structure and properties through advanced characterization. In situ X-ray absorption spectroscopy (XAS) serves as a powerful tool to probe both the active sites and structural evolution of catalytic materials under reaction conditions. In this review, we firstly provide an overview of the fundamental concepts of XAS and then comprehensively review the setup and application of in situ XAS, introducing electrochemical XAS cells, experimental methods, as well as primary functions on catalytic applications. The active sites and the structural evolution of M-N-C catalysts caused by the interplay with electric fields, electrolytes and reactants/intermediates during the oxygen evolution reaction and the oxygen reduction reaction are subsequently discussed in detail. Finally, major challenges and future opportunities in this exciting field are highlighted.

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