Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 22, Pages 6936-6939Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b03399
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Funding
- German Research Foundation [ME 1805/13-1]
- China Scholarship Council
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An efficient enantioselective addition of alkyl radicals, oxidatively generated from organotrifluor-oborates, to acceptor-substituted alkenes is catalyzed by a bis-cyclometalated rhodium catalyst (4 mol %) under photoredox conditions. The practical method provides yields up to 97% with excellent enantioselectivities up to 99% ee and can be classified as a redox neutral, electron transfer-catalyzed reaction.
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