Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 30, Pages 9377-9380Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05080
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Funding
- NSF Chemistry Division [CHE-1362454]
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Triplet ground-state organic molecules are interesting with respect to several emerging technologies but typically exhibit limited stability. We report two organic diradicals, one of which possesses a triplet ground state (2J/k(B) = 234 +/- 36 K) and robust stability at elevated temperatures. We are able to sublime this high-spin diradical under high vacuum at 140 degrees C with no significant decomposition.
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