Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 7, Pages 2086-2089Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b11706
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Funding
- National Science Foundation [CHE-0944634, CHE-1300299]
- Welch Foundation [A-1717]
- Fundamental Research Funds for the Central Universities of China [AUGA5710013115]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1300299] Funding Source: National Science Foundation
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The unexpectedly facile insertion of Rh or Ir into a B-Ph bond (reversible for Rh) converts a borane/bis(phosphine) precursor into a boryl/bis-(phosphine) PBP pincer ligand. Interconversions between the boryl/borane/borate central functionality are demonstrated in reactions with dihydrogen.
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