4.8 Article

Bis(1-Methyl-ortho-Carboranyl)Borane

Journal

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202307040

Keywords

Borane; Carborane; Cyclopropane; Hydroboration; Lewis Acid

Ask authors/readers for more resources

This passage describes a Lewis superacid called bis(1-methyl-ortho-carboranyl)borane, which can be rapidly synthesized in two steps. It is a highly effective hydroboration reagent capable of B-H addition to alkenes, alkynes, and cyclopropanes. To date, it is the first identified Lewis superacidic secondary borane and the most reactive neutral hydroboration reagent.
The Lewis superacid, bis(1-methyl-ortho-carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B-H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first identified Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available