Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 31, Pages 9783-9786Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b06239
Keywords
-
Categories
Funding
- NSF [CHE-1464941]
- NSF Divisions of Chemistry (CHE) and Materials Research (DMR) [NSF/CHE-1346572]
- Materials Research Collaborative Access Team (MRCAT)
- Sector 20
- DOE
- MRCAT
- U.S. Department of Energy
- Canadian Light Source
- U.S. DOE [DE-AC02-06CH11357]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1346572] Funding Source: National Science Foundation
Ask authors/readers for more resources
Mono(phosphine)-M (M-PR3; M = Rh and Ir) complexes selectively prepared by postsynthetic metalation of a porous triarylphosphine-based metal-organic framework (MOP) exhibited excellent activity in the hydrosilylation of ketones and alkenes, the hydrogenation of alkenes, and the C-H borylation of arenes. The recyclable and reusable MOF catalysts significantly outperformed their homogeneous counterparts, presumably via stabilizing M-PR3 intermediates by preventing deleterious disproportionation reactions/ligand exchanges in the catalytic cycles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
