Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 29, Pages 9101-9104Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b06053
Keywords
-
Categories
Funding
- West Light Foundation of the CAS [2015-XBQN-B-11]
- NSFC [51425206, U1129301]
- Xinjiang International Science & Technology Cooperation Program [20146001]
- Funds for Creative Cross & Cooperation Teams of CAS
- Xinjiang Key Laboratory Foundation [2014KL009]
- Science and Technology Project of Urumqi [51425206]
- National Science Foundation [DMR-1005827, DMR-1307698]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1307698] Funding Source: National Science Foundation
Ask authors/readers for more resources
LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very short absorption edge of A = 174 nm and generates the largest powder second harmonic generation (SHG) response for deep-UV phosphates that do not contain additional anionic groups, i.e., 2.6 times that of KH2PO4 (KDP). First-principles electronic structure analyses confirm the experimental results and suggest that the strong SHG response may originate from the aligned nonbonding O-2p orbitals. The discovery and characterization of LiCs2PO4 provide a new insight into the structure property relationships of phosphate-based nonlinear optical materials with large SHG responses and short absorption edges.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available