Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 24, Pages 7524-7527Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b04624
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Funding
- Singapore National Research Foundation
- GlaxoSmithKline
- Ministry of Education of Singapore
- Nanyang Technological University
- China's Ministry of Education
- National Key Program for Basic Research [2010CB 126105]
- Thousand Talent Plan
- National Natural Science Foundation of China [21132003, 21472028]
- Guizhou Province Returned Oversea Student Science and Technology Activity Program
- Science and Technology Department of Guizhou Province
- Guizhou University
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A carbene-catalyzed desymmetrization of prochiral bisphenol compounds bearing remote P-stereo genic centers is disclosed. The catalytic reactions can be performed on gram scales with 1 mol % N-heterocyclic carbene (NHC) catalyst, providing efficient access to enantiomerically enriched P-stereogenic phosphinates. The chiral phosphinates prepared with our method can find widespread applications as asymmetric organic catalysts and ligands.
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