Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 28, Pages 8718-8721Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05271
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- National Science Foundation [CHE-1151563]
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A general method for the hydropyridylation of unactivated alkenes is described. The transformation connects metal-mediated hydrogen atom transfer to alkenes and Minisci addition reactions. The reaction proceeds under mild conditions with high site-selectivities and allows for the construction of tertiary and quaternary centers from simple alkene starting materials.
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