Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 49, Pages 15857-15860Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b10836
Keywords
-
Categories
Funding
- NRF of Korea through the CRI Program [NRF-2012R1A3A2048842]
- NRF of Korea through the GRL Program [NRF-2010-00353]
- JSPS KAKENHI [16H02268]
- National Natural Science Foundation of China [21473226]
- National Research Foundation of Korea [NRF-2015H1D3A1066507]
- National Research Foundation of Korea [2012R1A3A2048842, 2015H1D3A1066507, 2010-00353] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Grants-in-Aid for Scientific Research [16H02268] Funding Source: KAKEN
Ask authors/readers for more resources
Photocatalytic enantioselective epoxidation of terminal olefins using a mononuclear non-heme chiral manganese catalyst, [(R,R-BQCN)Mn-II](2+), and water as an oxygen source yields epoxides with relatively high enantioselectivities (e.g., up to 60% enantiomeric excess). A synthetic mononuclear non-heme chiral Mn(IV)-oxo complex, [(R,R-BQCN)Mn-IV(O)](2+), affords similar enantioselectivities in the epoxidation of terminal olefins under stoichiometric reaction conditions. Mechanistic details of each individual step of the photoinduced catalysis, including formation of the Mn(IV)-oxo intermediate, are discussed on the basis of combined results of laser flash photolysis and other spectroscopic methods.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available