Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 43, Pages 14242-14245Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b09880
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- KACST
- NU
- International Institute for Nanotechnology at NU
- U.S. DOE, Office of Science, Basic Energy Sciences [DE-FG02-87ER13808]
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We describe the incorporation of a bistable mechanically interlocked molecule (MIM) into a robust Zr-based metal organic framework (MOF), NU-1000, by employing a post-synthetic functionalization protocol On average, close to two bistable [2]catenanes can be incorporated per repeating unit of the hexagonal channels of NU-1000. The reversible redox-switching of the bistable [2]catenanes is retained inside the MOF, as evidenced by solid-state UV-vis-NIR reflectance spectroscopy and cyclic voltammetry. This research demonstrates that bistable MIMs are capable of exhibiting robust dynamics inside the nanopores of a MOF;
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