Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 17, Pages 5531-5534Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b02747
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Funding
- National Science Foundation [CHE-1039925]
- Research Corporation (Cottrell College Science Award)
- NSF [DMR-1157490]
- State of Florida
- American Chemical Society Petroleum Research Fund
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The formally Co-IV carbene Co(OR)(2)(=CPh2) is formed upon the reaction of diphenyldiazomethane with the cobalt bis(alkoxide) precursor Co(OR)(2)(THF)(2). Structural, spectroscopic, and theoretical studies demonstrate that Co(OR)(2)(=CPh2) has significant high-valent Co-IV=CPh2 character with non-negligible spin density on the carbene moiety.
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