Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 29, Pages 9089-9092Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05706
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Funding
- Spanish Ministry of Economy and Competitiveness (MINECO) [MAT2013-45460-R, MAT2014-52085-C2-2, CTQ2014-61748-EXP]
- FPU scholarship from Spanish Ministry of Education, Culture and Sport
- Fundacion General CSIC (Programa ComFuturo)
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With the aim of developing new highly porous, heterogeneous Lewis acid catalysts for multi component reactions, a new mesoporous metal organic framework, InPF-110 ( [In3O(btb)(2)(HCOO)(L)] (H(3)btb = 1,3,5-tris(4-carboxyphenyl)benzene acid, L = methanol, water, or ethanol), has been prepared with indium as the metal center. It exhibits a Langmuir surface area of 1470 m(2) g(-1), and its structure consists of hexagonal pores with a 2.8 nm aperture, which allows the diffusion of multiple substrates. This material presents a large density of active metal sites resulting in outstanding catalytic activity in the formation of substituted alpha-aminonitriles through the one pot Strecker reaction of ketones. In this respect, InPF-110 stands out compared to other catalysts for this reaction due to the small catalyst loadings required, and without the need for heat or solvents. Furthermore, X-ray single crystal diffraction studies clearly show the framework substrate interaction through coordination to the accessible indium sites.
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