Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 35, Pages 11097-11100Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b06290
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Funding
- Shandong University [104.205.2.5]
- EPSRC [EP/J00135X/1]
- EPSRC [EP/J015156/1, EP/L023652/1, EP/H024107/1, EP/J00135X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J00135X/1, EP/L023652/1, EP/H024107/1, EP/J015156/1] Funding Source: researchfish
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By using solubility control to crystallize the prenucleation clusters of hydrosol, a family of titanium-oxo clusters possessing the {Ti18O27} core in which the 18 Ti(IV)-ions are uniquely connected with mu-oxo ligands into a triple-decked pentagonal prism was obtained. The cluster cores are wrapped by external sulfate and aqua ligands, showing good solubilities and stabilities in a variety of solvents including acetonitrile and water and allowing their solution chemistry being studied by means of electrospray ionization mass spectroscopy, O-17 NMR, and vibrational spectroscopy. Furthermore, this study provides new titanium oxide candidates for surface modifications and homogeneous photocatalysis.
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