Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 38, Pages 12344-12347Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b07969
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Funding
- National Science Foundation [CHE-1151991, CHE-1012636]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1308307, 1151991] Funding Source: National Science Foundation
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Metallomacromolecular architectural conversion is expanded by the characterization of three different structures. A quantitative, single-step, self-assembly of a shape-persistent monomer, containing a flexible crown ether moiety, gives an initial Archimedean-based cuboctahedron that has been unequivocally characterized by 1D and 2D NMR spectroscopy, mass spectrometry, and collision cross section analysis. Both dilution and exchange of counterions, transforms this cuboctahedron into two identical octahedrons, which upon further dilution convert into four, superposed, bistrianglar complexes; increasing the concentration reverses the process. Ion binding studies using the cuboctahedral cage were undertaken.
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