Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 12, Pages 4014-4017Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b02158
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Funding
- University of Geneva
- Swiss National Science Foundation
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A novel enantioselective Pd-catalyzed intermolecular carboetherification of dihydrofurans is reported. The in situ generation of chiral bis-phosphine mono-oxide ligands is crucial, and a general catalytic system has been identified based on this approach. It provides access to a variety of fused tetrahydrofurobenzofurans in consistently high yield and enantiomeric excess.
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