4.8 Article

Aging Property of Halide Solid Electrolyte at the Cathode Interface

Related references

Note: Only part of the references are listed.
Article Energy & Fuels

High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes

Laidong Zhou et al.

Summary: A series of new lithium mixed-metal chlorospinels are reported as solid electrolytes for all-solid-state lithium batteries, which exhibit high ionic conductivity and low electronic conductivity, showing potential for high-performance all-solid-state lithium batteries.

NATURE ENERGY (2022)

Article Electrochemistry

High Temperature Testing of NMC/Graphite Cells for Rapid Cell Performance Screening and Studies of Electrolyte Degradation

T. Taskovic et al.

Summary: This article investigates the charge-discharge cycling of LiNi0.5Mn0.3Co0.2O2/graphite cells with two different electrolytes at 70 degrees C. The results show that the degradation processes observed at 40 degrees C and 55 degrees C also occur at an accelerated rate at 70 degrees C. The dissolution of transition metals from the positive electrode is tracked using X-ray fluorescence studies. Elevated temperature testing at 70 degrees C is found to be a viable rapid screening technique for advanced electrolytes and advanced electrode materials.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

Article Chemistry, Physical

A Series of Ternary Metal Chloride Superionic Conductors for High-Performance All-Solid-State Lithium Batteries

Jianwen Liang et al.

Summary: Understanding the relationship between structure, ionic conductivity, and synthesis is crucial for developing superionic conductors. This study reports a series of Li3-3xM1+xCl6 solid electrolytes with orthorhombic and trigonal structures. The orthorhombic phase shows significantly higher ionic conductivity compared to the trigonal phase. Molecular dynamics simulations explain the enhanced ionic conductivity by the facile diffusion in the z-direction in the orthorhombic structure. All-solid-state batteries based on NMC811/Li2.73Ho1.09Cl6/In exhibit excellent electrochemical performance. The findings provide guidance for the design of halide superionic conductors.

ADVANCED ENERGY MATERIALS (2022)

Article Multidisciplinary Sciences

Compositionally complex doping for zero-strain zero-cobalt layered cathodes

Rui Zhang et al.

Summary: By using a new compositionally complex doping strategy, researchers have successfully fabricated a high-Ni, zero-Co layered cathode with extremely high thermal and cycling stability. The cathode exhibits nearly zero volumetric change, greatly reducing lattice defects and local strain-induced cracks. This study is of great significance for addressing the safety and stability concerns of high-Ni, zero-Co cathode materials.

NATURE (2022)

Article Physics, Applied

Detrimental effect of high-temperature storage on sulfide-based all-solid-state batteries

Kyungho Yoon et al.

Summary: The all-solid-state battery is a promising next-generation battery system, but its practical application requires consideration of temperature variations and electrolyte stability.

APPLIED PHYSICS REVIEWS (2022)

Article Chemistry, Multidisciplinary

Different interfacial reactivity of lithium metal chloride electrolytes with high voltage cathodes determines solid-state battery performance

Ivan Kochetkov et al.

Summary: A deep understanding of the interaction between the surface of cathode materials and solid electrolytes is crucial for designing advanced solid-state batteries. This study explores the impact of cationic metal substitution on the interfacial chemistry in Li-M-Cl solid electrolytes and establishes a platform for evaluating the stability of new halide solid electrolytes in SSB cells.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Nanoscience & Nanotechnology

Reaction of Li1.3Al0.3Ti1.7(PO4)3 and LiNi0.6Co0.2Mn0.2O2 in Co-Sintered Composite Cathodes for Solid-State Batteries

Jean Philippe Beaupain et al.

Summary: The study investigates the reaction between the solid electrolyte Li1.3Al0.3Ti1.7(PO4)(3) (LATP) and the active material LiNi0.6Co0.2Mn0.2O2 (NCM622) in all-ceramic oxide batteries through cosintering, which reveals that elemental diffusion and decomposition reactions occur even at low sintering temperatures, hindering the densification of the composite and the formation of ion-conducting paths between individual particles. Based on the experimental results, a mechanism of the reactions in cosintered LATP and NCM622 oxide composite cathodes is suggested.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

New Cost-Effective Halide Solid Electrolytes for All-Solid-State Batteries: Mechanochemically Prepared Fe3+-Substituted Li2ZrCl6

Hiram Kwak et al.

Summary: The new halide superionic conductors Li2ZrCl6 and Fe3+-substituted Li2ZrCl6 exhibit high Li+ conductivity, offering new possibilities for the development of all-solid-state batteries.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Three in One Strategy to Achieve Zirconium Doping, Boron Doping, and Interfacial Coating for Stable LiNi0.8Co0.1Mn0.1O2 Cathode

Ze Feng et al.

Summary: A three in one strategy using ZrB2 as a dopant is proposed to stabilize the crystal structure and surface of the Ni-rich cathode. Zr and B doping helps stabilize the crystal structure and prevent the formation of microcracks, while Zr also forms a coating with the surface lithium source to protect the surface and suppress interfacial phase transition.

ADVANCED SCIENCE (2021)

Article Electrochemistry

Study of Electrolyte and Electrode Composition Changes vs Time in Aged Li-Ion Cells

L. M. Thompson et al.

Summary: This study analyzed electrolyte and electrode compositions in a variety of battery cells tested under different conditions, revealing constant rates of increase in various products and reactants. Results from cells tested for 3 to 6 months could reasonably estimate the status of the cells after 12 months.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

A mechanistic investigation of the Li10GeP2S12|LiNi1-x-yCoxMnyO2 interface stability in all-solid-state lithium batteries

Tong-Tong Zuo et al.

Summary: Researchers investigated the degradation mechanisms at the LGPS/NCM622 interface and found that electronic transport limits the growth of the degradation layer at the electrode|electrolyte interface. Additionally, they demonstrated the presence of two oxidation mechanisms at medium (3.7 V vs. Li+/Li < E < 4.2 V vs. Li+/Li) and high (E > = 4.2 V vs. Li+/Li) potentials.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Material Design Strategy for Halide Solid Electrolytes Li3MX6 (X = Cl, Br, and I) for All-Solid-State High-Voltage Li-Ion Batteries

Kwangnam Kim et al.

Summary: This study systematically investigates the performance and stability of lithium halides Li3MX6 as solid electrolytes for high-voltage all-solid-state Li-ion batteries. The findings suggest that chlorides exhibit high oxidation potential and stability, making them suitable for high-voltage cathode materials.

CHEMISTRY OF MATERIALS (2021)

Article Chemistry, Physical

Single- or Poly-Crystalline Ni-Rich Layered Cathode, Sulfide or Halide Solid Electrolyte: Which Will be the Winners for All-Solid-State Batteries?

Yoonjae Han et al.

Summary: The use of single-crystalline NCA and oxidation-tolerable Li3YCl6 in all-solid-state batteries shows promising results in terms of discharge capacity, initial Coulombic efficiency, cycling performance, and rate capability. The overlooked contribution of side reactions to the degradation of polycrystalline NCA is revealed for the first time in this study through rigorous characterization and analysis.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Pliable Lithium Superionic Conductor for AllSolid-State Batteries

Sung-Kyun Jung et al.

Summary: The novel inorganic-based pliable solid electrolyte with clay-like features shows extraordinary mechanical properties and high lithium-ion conductivity, providing a solution for the challenges at the solid electrolyte-cathode interface in all-solid-state batteries.

ACS ENERGY LETTERS (2021)

Article Multidisciplinary Sciences

A universal wet-chemistry synthesis of solid-state halide electrolytes for all-solid-state lithium-metal batteries

Changhong Wang et al.

Summary: Solid-state halide electrolytes with high ionic conductivity were successfully synthesized using ammonium-assisted wet chemistry. Microstrain-induced microstructure changes were found beneficial for lithium ion transport. Alleviating interfacial incompatibility between halide electrolytes and lithium metal by transforming the interface led to the development of high-performance all-solid-state lithium-metal batteries.

SCIENCE ADVANCES (2021)

Article Materials Science, Multidisciplinary

Lithium Ytterbium-Based Halide Solid Electrolytes for High Voltage All-Solid-State Batteries

Se Young Kim et al.

Summary: A new metastable phase Li3YbCl6 and mixed-metal halide solid electrolytes Li3-xYb1-xZrxCl6 were discovered for high-voltage cathodes with good stability and high ionic conductivity. The high electrochemical oxidation stability of the mixed-metal halide solid electrolyte enables cycling with uncoated >4 V-class cathodes in all-solid-state cells.

ACS MATERIALS LETTERS (2021)

Article Chemistry, Multidisciplinary

Site-Occupation-Tuned Superionic LixScCl3+xHalide Solid Electrolytes for All-Solid-State Batteries

Jianwen Liang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

A new halospinel superionic conductor for high-voltage all solid state lithium batteries

Laidong Zhou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Lithium Chlorides and Bromides as Promising Solid-State Chemistries for Fast Ion Conductors with Good Electrochemical Stability

Shuo Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Water-Mediated Synthesis of a Superionic Halide Solid Electrolyte

Xiaona Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries

Xiaona Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Review Chemistry, Multidisciplinary

New horizons for inorganic solid state ion conductors

Zhizhen Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

Gas Evolution in All-Solid-State Battery Cells

Timo Bartsch et al.

ACS ENERGY LETTERS (2018)

Article Chemistry, Physical

Predicting accurate cathode properties of layered oxide materials using the SCAN meta-GGA density functional

Arup Chakraborty et al.

NPJ COMPUTATIONAL MATERIALS (2018)

Review Nanoscience & Nanotechnology

Lithium battery chemistries enabled by solid-state electrolytes

Arumugam Manthiram et al.

NATURE REVIEWS MATERIALS (2017)

Article Nanoscience & Nanotechnology

The Detrimental Effects of Carbon Additives in Li10GeP2S12-Based Solid-State Batteries

Wenbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Electrochemistry

Calendar Aging of Lithium-Ion Batteries I. Impact of the Graphite Anode on Capacity Fade

Peter Keil et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

Editorial Material Energy & Fuels

A solid future for battery development

Juergen Janek et al.

NATURE ENERGY (2016)

Article Energy & Fuels

High-power all-solid-state batteries using sulfide superionic conductors

Yuki Kato et al.

NATURE ENERGY (2016)

Article Chemistry, Multidisciplinary

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries

Yoshikatsu Seino et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Article Chemistry, Physical

Calendar and cycle life study of Li(NiMnCo)O2-based 18650 lithiumion batteries

Madeleine Ecker et al.

JOURNAL OF POWER SOURCES (2014)

Article Multidisciplinary Sciences

Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery

Atsushi Sakuda et al.

SCIENTIFIC REPORTS (2013)

Article Materials Science, Multidisciplinary

A high-throughput infrastructure for density functional theory calculations

Anubhav Jain et al.

COMPUTATIONAL MATERIALS SCIENCE (2011)

Article Chemistry, Physical

A lithium superionic conductor

Noriaki Kamaya et al.

NATURE MATERIALS (2011)

Article Physics, Applied

Crystal Structure of Indium and Lead under Confined Geometry Conditions

A. A. Naberezhnov et al.

TECHNICAL PHYSICS (2011)

Article Chemistry, Multidisciplinary

Li6PS5X: A class of crystalline Li-rich solids with an unusually high Li+ mobility

Hans-Joerg Deiseroth et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Physical

Interfacial modification for high-power solid-state lithium batteries

Kazunon Takada et al.

SOLID STATE IONICS (2008)

Article Chemistry, Physical

Main aging mechanisms in Li ion batteries

M Broussely et al.

JOURNAL OF POWER SOURCES (2005)

Article Chemistry, Physical

Aging mechanism in Li ion cells and calendar life predictions

M Broussely et al.

JOURNAL OF POWER SOURCES (2001)