Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 33, Issue 26, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202215066
Keywords
bipolar host materials; carrier transportation; low efficiency roll-off; meta-linkage; phosphorescent OLEDs
Ask authors/readers for more resources
Novel host materials PPI22PPPBO and PPI33PPPBO are designed with appropriate triplet energy levels (E-T) for phosphorescent organic light emitting diodes (PhOLEDs), leading to low turn-on voltages and high external quantum efficiency (EQE). Particularly, PPI33PPPBO demonstrates ordered face-to-face stacking, improving carrier mobility and reducing efficiency roll-offs. This study presents the first application of PBO in PhOLED host materials using a twisted connection method.
Novel host materials and their molecular design methods for phosphorescent materials are crucial for the application of phosphorescent organic light emitting diodes (PhOLEDs), which require balanced carrier injection and sufficient triplet energy levels (E-T). Herein, two host materials, namely PPI22PPPBO and PPI33PPPBO, are designed by varying the linkage of benzoxazole (PBO) and phenanthroimidazole (PPI) groups with appropriate E-T for green, yellow, and red phosphors. The meta-link PPI33PPPBO is not only of smaller pi-conjugation, but also of more ordered face-to-face stacking for enhanced and more balanced carrier mobility. As a result, the green, yellow, and red PhOLEDs utilizing PPI33PPPBO as host materials show low turn-on voltages of 2.8 V. The maximum external quantum efficiency (EQE(max)) of the corresponding devices reaches 22.8%, 26.7%, and 17.6%, which is superior to that of the traditional host materials CBP and mCP, showing great application potential. More importantly, when the luminance is 1000 cd m(-2), their EQE can still be as high as 21.9%, 25.5%, and 16.4%, corresponding to negligible efficiency roll-offs of only 3.9%, 4.5%, and 6.8%. To the best of authors knowledge, it is the first time that PBO is applied to PhOLED host materials using a twisted connection method.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available