Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 45, Pages 14864-14867Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b10297
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Funding
- National Natural Science Foundation of China [21472083]
- Nanjing University
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An effective palladium-catalyzed regioselective hydroformylation of olefins with formic acid is described. The ligand plays a crucial role in directing the reaction pathway. Linear aldehydes can be obtained in up to 93% yield with >20:1 regioselectivity using 1,3-bis(diphenylphosphino)propane (dppp) as the ligand. The reaction process is operationally simple and requires no syngas.
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