Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 14, Pages 4710-4713Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b01244
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Funding
- National Natural Science Foundation of China [21172249, 21472225]
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It is very important to create novel topologies and improve structural complexity for covalent organic frameworks (COFs) that might lead to unprecedented properties and applications. Despite the progress achieved over the past decade, the structural diversity and complexity of COFs are quite limited. In this Communication, we report the construction of COFs bearing three different kinds of pores through the heterostructural mixed linker strategy involving the condensation of a D-2h-symmetric tetraamine and two C-2-symmetric dialdehydes of different lengths. The complicated structures of the triple-pore COFs have been confirmed by powder X-ray diffraction and pore size distribution analyses.
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