Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 138, Issue 7, Pages 2186-2189Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b00541
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- National Institute of General Medical Sciences [R01GM098601, 1F31GM113494]
- NSF
- NIH
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The first total synthesis of a chromodorolide diterpenoid is described. The synthesis features a bimolecular radical addition/cyclization/fragmentation cascade that unites butenolide and trans-hydrindane fragments while fashioning two C-C bonds and stereo selectively forming three of the ten contiguous stereo centers of chromodorolide B.
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