Journal
ACS APPLIED MATERIALS & INTERFACES
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c20276
Keywords
cucurbituril; dissipative self-assembly; molecular machine; organelle imaging; pseudorotaxane
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Here we report light-activated convertible pseudorotaxanes (PRs) that can self-assemble and show tunable fluorescence, enabling deformable nano-assemblies. When exposed to light, a specific combination of molecules transform into a transient form, which can thermally relax to its original form in the dark, accompanied by periodic fluorescence changes. The self-assembly of these PRs leads to the formation of octahedral and spherical nanoparticles, which can be used for dynamic imaging of the Golgi apparatus.
Developing an artificial dynamic nanoscale molec-ular machine that dissipatively self-assembles far from equilibrium is fundamentally important but is significantly challenging. Herein, we report dissipatively self-assembling light-activated convertible pseudorotaxanes (PRs) that show tunable fluorescence and enable deformable nano-assemblies. A pyridinium-conjugated sulfonato-merocyanine derivative (EPMEH) and cucurbit[8]uril (CB[8]) form the 2EPMEH subset of CB[8] [3]PR in a 2:1 stoichiometry, which phototransforms into a transient spiropyran containing 1:1 EPSP subset of CB[8] [2]PR when exposed to light. The transient [2]PR thermally relaxes (reversibly) to the [3]PR in the dark accompanied by periodic fluorescence changes that include near-infrared emission. Moreover, octahedral and spherical nanoparticles are formed through the dissipative self-assembly of the two PRs, and the Golgi apparatus is dynamically imaged using fluorescent dissipative nano-assemblies.
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