Journal
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN
Volume 74, Issue 11, Pages 1058-1068Publisher
SOC SYNTHETIC ORGANIC CHEM JPN
DOI: 10.5059/yukigoseikyokaishi.74.1058
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- Japan Science and Technology Agency (JST)
- Astellas Foundation for Research on Metabolic Disorders
- Yakugaku Shinkoukai
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This personal account summarizes our recent progress in the development of C-H transformations. We achieved ortho-selective C-H borylation and silylation using Lewis acid-base interaction between two substrates, and meta-selective C-H borylation using hydrogen bonding between a hydrogen donor unit of a ligand and a substrate functional group. Regioselective C-H trifluoromethylation and related reactions of 6 membered heteroaromatic compounds were realized at the 2-, 4-, and benzylic-positions of the heteroaromatic rings. In addition, we developed C-H transformations directed towards the synthesis of organic functional materials, such as highly soluble polyimides and Tc-conjugated molecules containing either heteroatom(s) or a Lewis acid-base interaction.
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