Journal
MOLBANK
Volume 2023, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/M1539
Keywords
substituted catecholate complex; hexacoordinated silicon; intermolecular interactions; supramolecular organization; single-crystal X-ray diffraction
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An X-ray diffraction study was conducted on the transesterification product of N-methyl-N-(trimethoxysilylmethyl)acetamide with 4,5-dibromobenzene-1,2-diol. It was found that the coordination polyhedron of the silicon atom in the anionic complex was a distorted octahedron disordered by the superposition of Delta and Λ optical isomers. Various hydrogen donor groups in the bis(cyclohexyl)ammonium cations, solvent ethanol molecules, and non-coordinated 4,5-dibromobenzene-1,2-diol led to the formation of H-bonded chains, while dibromobenzenediol also participated in stacking interactions.
An X-ray diffraction study of a transesterification product of N-methyl-N-(trimethoxysilylmethyl)acetamide by 4,5-dibromobenzene-1,2-diol was carried out. It was established that the coordination polyhedron of the silicon atom in an anionic complex is a distorted octahedron disordered due to the superposition of the Delta and ? optical isomers. The presence of various hydrogen donor groups in bis(cyclohexyl)ammonium cations, solvent ethanol molecules, and non-coordinated 4,5-dibromobenzene-1,2-diol caused the formation of H-bonded chains, while dibromobenzenediol also took part in stacking interactions.
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