Possibility of Emergence of Chiral Magnetic Soliton in Hexagonal Metal Formate [NH4][M(HCOO)3] with M2+ = Mn, Fe, Co, and Ni and KCo(HCOO)3

Search of chiral magnetic solitons on the basis of the data on the crystal structure is important from both fundamental and technological points of view. Potential chiral magnetic solitons-hexagonal metal formates [NH4][M(HCOO)(3)] with M2+= Mn, Fe, Co, and Ni and KCo(HCOO)(3) containing dominating left-handed chiral antiferromagnetic helices that compete with interhelix interactions have been identified. The sign and strength of magnetic interactions not only between nearest neighbors but also for longer-range neighbors in the metal formates have been calculated on the basis of structural data. Magnetic structures of these compounds are similar to that of the chiral magnetic soliton Cr1/3NbS2. The interrelation between chiral polarization of crystalline and magnetic structures in the metastable polymorph KCo(HCOO)(3) has been demonstrated.