3.8 Article

Characterization of PAN-TiO2 Nanofiber Mats and their Application as Front Electrodes for Dye-sensitized Solar Cells

Journal

TEKSTILEC
Volume 65, Issue 4, Pages 298-306

Publisher

UNIV LJUBLJANI, FAC NATURAL SCI & ENGINEERING, DEPT TEXTILES
DOI: 10.14502/tekstilec.65.2022081

Keywords

dye-sensitized solar cells (DSSC); long-term stability; electrospinning; polyacrylonitrile (PAN); TiO2 nanoparticles

Funding

  1. German Federal Ministry for Economic Affairs and Climate Action via the AiF [KK5044902SY0]

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This paper investigates a needle electrospun nanofiber mat containing polyacrylonitrile and titanium dioxide nanoparticles. The dyed nanofiber mat is used as a front electrode for a dye-sensitized solar cell, providing stable results over two months.
In the context of the energy transition to renewables, the spotlight is on large systems connected to the power grid, but this also offers room for smaller, more specialized applications. Photovoltaics, in particular, offer the possibility of the self-sufficient supply of smaller electrical appliances on smaller scales. The idea of making previously unused surfaces usable is by no means new, and textiles such as backpacks, tent tarpaulins and other covers are particularly suitable for this purpose. In order to create a non-toxic and easily recyclable product, dye-sensitized solar cells (DSSC), which can be manufactured through electrospinning with a textile feel, are an attractive option here. Therefore, this paper investigates a needle electrospun nanofiber mat, whose spin solution contains polyacrylonitrile (PAN) dissolved in dimethyl sulfoxide (DMSO) as well es TiO2 nanoparticles. In addition to characterization, the nanofiber mat was dyed in a solution containing anthocyanins to later serve as a front electrode for a dye-sensitized solar cell. Although of lower efficiency, the DSSC provides stable results over two months of measurement.

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