4.8 Article

Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)

Journal

ADVANCED MATERIALS
Volume 28, Issue 7, Pages 1517-1522

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201504705

Keywords

2D materials; conducting polymers; supercapacitors; titanium carbide

Funding

  1. Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, and Office of Basic Energy Sciences

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Heterocyclic pyrrole molecules are in situ aligned and polymerized in the absence of an oxidant between layers of the 2D Ti3C2Tx (MXene), resulting in high volumetric and gravimetric capacitances with capacitance retention of 92% after 25 000 cycles at a 100 mV s(-1) scan rate.

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