Electrical properties and water incorporation in A-site deficient perovskite La1-xBaxNb3O9-0.5x

Barium doped A-site deficient perovskites La1-xBaxNb3O9-0.5x (x=0-0.05) were synthesized by the solid state method, their structure, electrical properties and state of oxygen-hydrogen groups have been investigated. These phases were found to be able to incorporate water from the gas phase and to exhibit proton transport. Hydration is accompanied by the formation of different forms of oxygen-hydrogen groups: OH- - groups and H3O+ - ions. The total conductivities of doped samples increased in a wet atmosphere due to the appearance of proton current carriers (at the temperatures below 700 degrees C), but the conductivity increased insignificantly (similar to 0.25 order of magnitude) because of a low doping level and, consequently, small concentration of protons. TG-measurements confirmed relatively low water content (below 0.2%). The total conductivity depends substantially on x and exhibits a minimum on sigma-f(x) dependencies. It has been suggested that such behavior is a manifestation of a mixed cation effect. (C) 2016 Elsevier Inc. All rights reserved.